GEO-03\INT-10 The geochemical and biological study of corals
Monthly resolved coral barium isotopes record increased riverine inputs during the South Asian summer monsoon
Yang Yu* , GEOMAR Helmholtz Centre for Ocean Research Kiel
Ed Hathorne, GEOMAR Helmholtz Centre for Ocean Research Kiel
Christopher Siebert, GEOMAR Helmholtz Centre for Ocean Research Kiel
Thomas Felis, MARUM - Center for Marine Environmental Sciences, University of Bremen
C.P. Rajendran, National Institute of Advanced Studies
Martin Frank, GEOMAR Helmholtz Centre for Ocean Research Kiel

We present a monthly resolved stable Ba isotope record (D138Bacoral) of a young fossil coral (Porites) from the eastern side of the Andaman Islands (NE Indian Ocean), which grew prior to the 19th century. This D138Bacoral record complements 19 years of monthly resolved Ba/Cacoral, Sr/Cacoral, U/Cacoral, D18Ocoral and D13Ccoral data from the same colony that can serve as a baseline of environmental variability before the industrialised era. The D138Bacoral record exhibits small but significant seasonal variability ranging from 0.16 to 0.27 ± 0.03‰ over two continuous annual cycles. The D138Bacoral signature is generally low during the South Asian summer monsoon (SAM, June-September) and post-SAM seasons (October-January), which are characterised by high Ba/Cacoral and more depleted D18OSW values. We suggest that Ba desorption from suspended fluvial sediments followed by lateral advection are the main causes of the low D138Bacoral and elevated Ba/Cacoral values during the SAM and post-SAM. However, this promising Ba proxy behaviour is interrupted by pronounced spikes of low D138Bacoral and high Ba/Cacoral signatures observed during the pre-SAM season (February-May) throughout the 19-year record. Possible explanations for these spikes observed during dry seasons are (1) Ba enrichment associated with decreased mixed layer depth or (2) Ba release from sediments trapped by local fringing mangroves. Surface seawater from the coral site sampled over an annual cycle exhibits a wide range of dissolved D138BaSW and [Ba]SW values, with significantly lowered D138BaSW of 0.29 ± 0.04‰ and high [Ba]SW of 66.03 nmol/kg during the SAM, which is broadly consistent with the coral skeletal signals. Our results establish a clear link between monsoon-driven freshening events and Ba isotope variability of surface waters and assess the utility of coral skeletal Ba isotopes to trace riverine inputs into tropical coastal oceans.